Why You Shouldn't Mix Baking Soda and Vinegar for Cleaning, According to a Chemist (2024)

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Ashley Abramson

Ashley Abramson

Ashley Abramson is a writer-mom hybrid. Her work, mostly focused on health, psychology, and parenting, has been featured in the Washington Post, New York Times, Allure, and more. She lives in the Milwaukee suburbs with her husband and two young sons.

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updated Apr 5, 2021

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Why You Shouldn't Mix Baking Soda and Vinegar for Cleaning, According to a Chemist (1)

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Some of the most effective household cleaners aren’t meant to be mixed. You probably already know never to combine harsh chemicals like bleach and ammonia (or really, bleach and anything). But common pantry essentials that are often used for cleaning — like baking soda and vinegar — shouldn’t be mixed either.

Unlike the bleach-ammonia mixture, combining soda and vinegar won’t hurt anyone — but don’t expect the mixture to do a good job cleaning, either. According to Amanda Morris, associate chair of the chemistry department at Virginia Tech University, baking soda and vinegar basically cancel each other out when they’re mixed —unless you use them the right way, in the right time frame.

Why, you ask? Here’s a little chemistry lesson, compliments of Dr. Morris.

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What Happens When You Mix Baking Soda and Vinegar?

Let’s start with the basics (literally). Baking soda is a base, and vinegar is an acid. When they’re combined, acids “donate” protons to bases; in this case, it’s acetic acid lending a hydrogen proton to the bicarbonate. When bicarbonate gains a hydrogen proton, it forms carbonic acid (or H2CO3) which is unstable and eventually decomposes. Once that happens you’re left with water, carbon dioxide, and acetate and sodium ions. The carbon dioxide gained in the reaction is what makes it bubbly, which looks appealing. But once the bubbles stop, you’re left with what Morris describes as “glorified water.”

Can You Clean With a Mix of Baking Soda and Vinegar?

Technically yes, but it’s not the power cleaner you’ve been led to believe. In fact, it’s volatile, and only really has one benefit: the mechanical movement of the bubbles.

If you’re planning to use baking soda and vinegar together, Morris suggests using the mixture while it’s still bubbling –and ideally, directly on the surface you’re cleaning. For example, one useful method Morris suggests is to dump a bit of baking soda down a garbage disposal, followed by a couple glugs of vinegar. The CO2 from the reaction will create bubbles, which are useful for manually dislodging gunk from your drain, or other places you can’t reach with a scrub brush.

Technically, as long as you use your mixture while it’s still bubbling —and still slightly basic — you can use it to cut through grease on kitchen surfaces. But it’s the basic baking soda doing the heavy lifting here, and a simple paste of baking soda and water would be better at cutting grease; the added vinegar only harms the power of your mixture.

By the time the vinegar and baking soda mixture stops bubbling, it won’t be all that helpful. “The way you wouldn’t want to use these ingredients is to mix them and let them sit in a bottle forever,” Morris says. “At that point, you essentially have water.”

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If Baking Soda and Vinegar Cancel Each Other Out, Why Do People Mix Them?

Irina Nikiforova, owner of Rocket Maids LA, says she often sees clients attempt to clean their ovens and cooktops with the mix. Other people, she says, clean shower doors with pre-mixed vinegar and baking soda with 0000 steel wool (which she says actually does the trick, probably because of the steel wool). Nikiforova suspects people see the bubbles in the reaction and assume it’s an effective cleaner, even after the reaction stops; or, people just assume that because the two ingredients are great for cleaning on their own, they’re even better together.

But she agrees with Morris that the best, most effective way to use baking soda and vinegar is separately, taking advantage of each one’s chemical properties. For example, as a base, baking soda is a great degreaser, and vinegar’s acid will cut through hard water stains.

If you’re looking for a green solution to clean your oven or cooktop, Nikiforova suggests simply creating a paste of water and baking soda, applying it to your oven for a few hours, and scrubbing the tough spots with a scouring stick.

And if you can’t use your baking soda-vinegar mix right away, as Morris suggests, save the chemical reaction for an at-home science experiment.

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Why You Shouldn't Mix Baking Soda and Vinegar for Cleaning, According to a Chemist (2024)

FAQs

Why You Shouldn't Mix Baking Soda and Vinegar for Cleaning, According to a Chemist? ›

Baking soda is a base, and vinegar is an acid. When they're combined, acids “donate” protons to bases; in this case, it's acetic acid lending a hydrogen proton to the bicarbonate. When bicarbonate gains a hydrogen proton, it forms carbonic acid (or H2CO3) which is unstable and eventually decomposes.

Why should you never mix baking soda and vinegar? ›

Baking Soda + Vinegar

While mixing baking soda with vinegar is not inherently dangerous, mixing them in a sealed container or spray bottle can cause a small explosion as the carbon dioxide tries to escape, not unlike when you shake a seltzer can and open it.

Is mixing vinegar and baking soda harmful? ›

Although mixing vinegar and baking soda is not considered dangerous, you should still avoid mixing these in a container. Vinegar is acidic and basic soda is basic, so the by-products are sodium acetate, carbon dioxide, and water that are not toxic.

Can vinegar and baking soda be mixed for cleaning? ›

For most purposes, Harris recommends combining one part baking soda with two parts white vinegar. That combo can cut through grease and lift stains, sometimes better than store-bought cleaners, she says. Important: Never combine vinegar with bleach.

Is it pointless to mix baking soda and vinegar? ›

But people also frequently mix vinegar and baking soda to produce a reportedly effective household cleaner. Unfortunately, the chemistry behind the bubbly reaction doesn't support the cleaning hype. The fizzy action is essentially a visual “placebo”, formed by the combination of an acid and a base.

Why you shouldn't clean with baking soda and vinegar? ›

Baking soda is a base, and vinegar is an acid. When they're combined, acids “donate” protons to bases; in this case, it's acetic acid lending a hydrogen proton to the bicarbonate. When bicarbonate gains a hydrogen proton, it forms carbonic acid (or H2CO3) which is unstable and eventually decomposes.

What two cleaning products should never be mixed? ›

Dangers of Mixing Household Chemical Cleaners
  • Bleach + Vinegar = Chlorine gas. This can lead to coughing, breathing problems, burning and watery eyes. ...
  • Bleach + Ammonia = Chloramine. ...
  • Bleach + Rubbing alcohol = Chloroform. ...
  • Hydrogen peroxide + Vinegar = peracetic/ peroxyacetic acid.

Why should you never use baking soda and vinegar to unclog a drain? ›

Consistent use of acidic solutions, like vinegar, can accelerate the corrosion of these metal pipes, leading to weakened integrity and potential breaks or leaks over time. The reaction between baking soda and vinegar can also produce salt, which may further contribute to the corrosion process.

Can I mix vinegar and baking soda in the washing machine? ›

Although vinegar and baking soda shouldn't be harmful to your washing machine if used in moderate amounts, extreme use can impact some of the coatings on the drive shaft components, which are the parts responsible for switching cycles from agitate to spin.

Can you mix vinegar and baking soda to clean mold? ›

The important thing is to mix the baking soda and vinegar in a 2:1 ratio (that is, twice as much baking soda as vinegar). This method eventually involves vigorous scrubbing with a gritty paste, which may damage softer materials like wallboard or finished wood.

Which cleans better vinegar or baking soda? ›

Baking soda is a natural deodorizer and a fine abrasive, which makes it excellent at scrubbing as well as absorbing odours. As a mild acid, vinegar is able to dissolve mineral deposits, dirt, grease, and grime.

What happens if you accidentally mix hydrogen peroxide and vinegar? ›

When vinegar of any kind is mixed in the same container with hydrogen peroxide, periacetic acid is formed. Periacetic acid is used as a sanitizer, but in high concentrations it is corrosive and can cause irritation of the skin, eyes and respiratory system.

What other cleaning agent should you never mix vinegar with? ›

Things You Should Never Mix With Vinegar When Cleaning Your Home
  • Bleach. Most commercially sold house cleaning bleaches contain sodium hypochlorite, which is a liquid form of chlorine. ...
  • Hydrogen peroxide. ...
  • Ammonia. ...
  • Other Home Cleaning Products.
Jul 19, 2023

What actually happened when the vinegar mixed with baking soda? ›

Sodium bicarbonate and acetic acid reacts to carbon dioxide, water and sodium acetate. The solid baking soda was placed in liquid vinegar producing carbon dioxide gas, which is evident because of the formation of bubbles in the foaming mixture.

What can you not clean with baking soda? ›

7 things you should never clean with baking soda
  • Glass/mirrors. Woman cleaning a window with cloth and spray (Image credit: Shutterstock) ...
  • Hardwood floors and wood furniture. ...
  • Marble or quartz countertops. ...
  • Gold plated dinnerware. ...
  • Ceramic stovetop/oven. ...
  • Aluminium cookware. ...
  • Items with deep grooves or cracks.
Jan 25, 2023

What is the ratio of baking soda to vinegar for cleaning? ›

You should use a ratio of 1:2 baking soda to vinegar. In other words, if you're using ½ cup of baking soda, use 1 cup of vinegar, or if you're using a cup of baking soda, use 2 cups of vinegar.

What happens when baking soda is added to vinegar? ›

A chemical reaction between the vinegar and the baking soda produces bubbles of carbon dioxide gas. The dish detergent in the vinegar helps the bubbles last longer than they would with just vinegar and baking soda.

When vinegar and baking soda react together? ›

When vinegar reacts with baking soda, it creates carbon dioxide bubbles, which act as leavening agents. So as the batter bakes, these tiny bubbles expand, causing the cake to rise and giving it that light, airy texture we all love.

Can I add baking soda and vinegar to my laundry? ›

With baking soda: Vinegar and baking soda neutralize each other, so you won't get the benefits of either if you run them simultaneously. You can, however, add baking soda to your laundry in the wash cycle and white vinegar to the rinse cycle—just don't add them anywhere together.

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